Homemade sea water for testing an ROV

March 16, 2014

Our GHCHS Algilata OpenROV project is not located near the ocean.   The OpenROV community has found that salt water operation can be flakey compared to fresh water due to low resistance between the salt water and  external wires that connect the battery tubes and the motors.     This post deals with making simulated sea water for testing the OpenROV in the lab.

Sea water conducts electricity due to the dissolved salts that produce ions for transporting charge between conductors submerged into the water.   Typical sea water has 35 parts per thousand  by weight of salt in water.    Since water at standard conditions weighs 1000 grams/liter then we can say that sea water has 35g of salt per liter.

I wanted to use just a cup measure to make a batch of sea water.     So I weighed one cup some Himalayan salt and found that it weighed 8 oz.  So we can estimate the weight of salt using this ratio…about 1  avoirdupois oz weight per 1  fluid oz .   Of course this will vary with the granularity of the salt due to variations in packing density but it should be good enough for conductivity testing.

Given that there are 28.3 grams per avoirdupois oz and  33.8 fluid oz per liter the sea water concentration of 35 gm per liter converts to  1.24 avoirdupois oz per 33.8 fluid oz or

1 avoirdupois oz per 27.2 fluid oz.

Since 1 cup (8 fl oz) of Himalayan salt weighed 8 avoirdupois oz then I would need to mix this with 217.6 fluid oz of water or 27.2 cups of water (1.7 gallons)

So I now have a simple rule of thumb for adding granulated salt to water using a volume measure:

volume ratio salt:water  1 : 27.2 

Other useful equivalents:   5.7 oz salt per gallon of water

                                              1/4 cup salt to 6 3/4  cup water

                                             1 tablespoon  salt to  1.7 cups water

Measuring salinity using conductivity:

Scientist often use conductivity to estimate salinity.   Standard units of conductivity are Siemans/meter  (S/m).    The electrical conductivity of 35 ppt salt water at a temperature of 15 °C is 42.9 mS/cm  (ref).   Thus 35 ppt equates to 42.9 mS/cm.

File:Conductimetrie-schema.png

Taken from wikipedia

Conductivity measurements assume that there are two parallel electrical plates of area A in water at a distance L apart.   If a voltage (V) is put across the plates and the current flow (I) measured then the conductivity  k = I/V*L/A =  L/(R*A)  where R is the resistance V/I.    Under ideal conditions the conductivity between the ROV wires and the water should be very low (high resistivity) but if a small area of copper is exposed  then conduction can occur. eg  some OpenROV forum members are finding resistance on the order of kiloohms rather than megohms.

Practically, if you put two probes from an ohm meter into water, the measured resistance will depend upon the area of the probe submerged and the distance between them.   You can use this as a reference to test your simulated sea water at home.

conductivity plug testerI made a simple  crude conductivity  instrument out of a two prong to three prong electrical plug adapter.   The plug prongs are separated by 1 cm and the exposed area between the prongs is almost exactly 1 sq sm.  I covered the non-facing sides with tape or you  could use paint or nail polish to insulate the surfaces from water.   See photo.

In the field,  dip the plug tester prongs into the water and measure the resistance between them.  Note the temperature since conductivity varies a lot with temperature.

Theoretical  plug conductivity prediction for sea water.

k = L/(R*A)  = 1/R            S/cm

= 1000/R    mS/cm

Typically sea water resistance in ohms for this homemade instrument  at 15 deg C would be

R_ohms = L/(A*k)= 1cm/(1cm ^2)/(42.9 mS/cm) = 1000/42.9 = 23.3 ohms

When creating your simulated sea water at  home you would like to have similar conditions.   You would add salt to your water tank/tub until the resistance level matched.

Testing:

I did a quick conductivity test by dissolving 1 tablespoon of Himalayan sea salt in 1 3/4 cups of water.   The measured resistance  using my plug conductivity tester was around 3 kohms with a VOM meter and using the voltage / current method the resistance was 230 ohms.     So it is reading much higher than the theory.    The test was done at 70F (21C).   Temperature changes the conductivity about 2% per degree.  The measurement was 6 deg C higher so at most we would expect a 12%  increase over the 15 C reference.

The absolute measurements can vary too much with conductivity so I would recommend just using the 35g/kg  salt/water mixing method or just doing relative conductivity measurements..i.e.  matching field conductivity to home conductivity under similar conditions.

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